Zincian h~gbomite (ZnO 3.5-10.5wt.%) occurs as an accessory phase in garnet quartzite that is intimately associated with the Broken Hill and Black Mountain Cu-Pb-Zn-Ag deposits, Aggeneys, South Africa. H6gbomite coexists with a number of minerals including quartz, gahnite, sillimanite, sphalerite, pyrrhotine, pyrite, magnetite, and ilmenite, suggesting that h6gbomite may have formed by sulphidation and oxidation reactions. Such reactions may account for the high Zn content of h6gbomite. Where associated with metamorphosed massive sulphide deposits h6gbomite is enriched in Zn relative to that found in ultramafics, Fe-Ti deposits, Fe ores, aluminous metasediments, and skarns. This enrichment in h6gbomite constitutes a potential exploration guide for metamorphosed massive sulphide deposits.