The unstable flow phenomenon in injection molding and
the resulting
flow marks adversely affect the application of polymer products. Therefore,
it is important and necessary to study the unstable flow to clarify
the generation mechanism of the flow marks. In this work, the development
of unstable flow in injection molding of the polypropylene/polyolefin
elastomer (PP/POE) blend was investigated through short shot injection
molding experiments. The results show that the melt flows stably at
the early stage, and then, the flow front of the melt begins to fluctuate
along the thickness direction, resulting in the formation of an unstable
flow of the melt and periodic concave and convex regions on the surface
of short shot samples. The relationship between the generation of
flow marks and the development of unstable flow was also clarified,
that is, the convex and concave regions formed during the filling
process evolve into the cloudy and glossy regions of the flow marks,
respectively. Since the melts in different regions experience different
shear and thermal histories, the orientation degree of the dispersed
phase and the crystal in the cloudy region is higher than that in
the glossy region, while the glossy region has a higher crystallinity
and lamellar thickness. Ultimately, a more refined unstable flow model
for the generation mechanism of flow marks was proposed..