The degradation of structural performance due to reinforcement corrosion in reinforced concrete (RC) structures and the subsequent measures to improve the mechanical properties of corroded RC structures have garnered significant interest. This study investigates the structural performance of corroded polypropylene fiber RC slabs through both experimental and numerical approaches. Specimens were subjected to accelerated corrosion via electrochemical methods to simulate rebar corrosion. Key experimental parameters include polypropylene fiber volume fractions of 0% and 3%, design corrosion levels of 0%, 5%, and 10%, and both one-way and two-way constraints. The Digital Image Correlation (DIC) technique was employed for data acquisition. Load, deflection, strain, and crack morphology data were collected during loading. Results indicate that reinforcement corrosion increases the maximum crack width during loading, while a 3% polypropylene fiber volume fraction reduces this width by 20% to 48% at the same load level. Polypropylene fibers also enhance the peak loads and corresponding deflections of unidirectional and bidirectional specimens, with a more pronounced increase in unidirectional specimens of 11.3% and 15.4%, respectively. Although corrosion reduces the load-carrying capacity of the specimens, the inclusion of 3% polypropylene fibers significantly mitigates this reduction. A numerical model, incorporating rebar corrosion and polypropylene fibers through appropriate material constitutive models, was developed and validated against experimental results. The model accurately simulates the mechanical behavior of polypropylene fiber RC slabs with corroded reinforcement.