NO
x
are one of the most important pollutants produced during combustion of fossil fuels. Emissions of NO
x
from combustion systems are primarily in the form of nitric oxides (NO). They are generally produced from the oxidation of the nitrogen contained in the atmospheric air or by the oxidation of the nitrogen‐bounded compounds in the fuel. NO is the main compound produced from the combustion; however, once it has been released in the atmosphere, it rapidly reacts producing NO
2
, which is more stable than NO. For this reason, NO
2
are generally regulated as representative NO
x
compound. In general, NO
x
are toxic, they also react to form smog and acid rain, and they play a central role in the formation of ozone in the troposphere. In addition, NO
x
, is a major greenhouse gas.
This article reviews the mechanisms that govern the formation of NO
x
emissions from fossil fuels combustion and the main transformations in the atmosphere. Thermal, prompt, and fuel NO
x
mechanisms are presented. Finally, the modern technologies for mitigating the NO
x
emissions from power systems are presented, divided as precombustion, combustion modifications, and postcombustion techniques.