The dispersive properties of waves are strongly affected by inevitable residual disorder in man-made propagating media, in particular in the slow wave regime. By a direct measurement of the dispersion curve in k space, we show that the nature of the guided modes in real photonic crystal waveguides undergoes an abrupt transition in the vicinity of a band edge. Such a transition that is not highlighted by standard optical transmission measurement, defines the limit where k can be considered as a good quantum number. In the framework of a mean-field theory we propose a qualitative description of this effect and attribute it to the transition from the "dispersive" regime to the diffusive regime. In particular we prove that a scaling law exists between the strength of the disorder and the group velocity. As a result, for group velocities v g smaller than c / 25 the diffusive contribution to the light transport is predominant. In this regime the group velocity v g loses its relevance and the energy transport velocity v E is the proper light speed to consider.