“…Their activity resulted in the formation of thick volcaniclastic sequences over which heavily populated areas are presently located, including the capital of Ecuador, Quito (Hall and Mothes, 2008b). Several authors also pointed out a possible link between the spatial distribution of volcanism and its geochemical variability, in relation to the subduction of the Carnegie Ridge, crustal tectonics, and the slab geometry (e.g., Litherland and Aspden, 1992; Barberi et al, 1988;Gutscher et al, 1999;Samaniego et al, 2002Samaniego et al, , 2005 Recently, several geochronological studies shade light on the development of ancient volcanism with emphasis on the southern termination of the arc, and its central and northern segments (e.g., Bablon et al, 2019Bablon et al, , 2020aSantamaría et al, 2023). In this work, in addition to compiling radiometric ages at the arc scale, we especially focus on the central zone of the arc, which has a relatively limited number of dated volcanic complexes.…”