In order to endow road materials with environmental protection properties such as automobile exhaust purification, a protective environmental micro-surfacing material with exhaust purification was prepared. Functional materials with photocatalytic activity were prepared by sol-gel method. The best preparation scheme of composite modified asphalt was determined by comparative test. The mix proportion of micro-surfacing mixture was designed to determine the optimal preparation process of micro-surfacing. Based on rutting test, wet wheel wear test and pendulum test, the road performance of protective environmental micro-surfacing with exhaust purification function is studied. An exhaust gas purification test equipment is improved to determine the test method and analyze the exhaust gas purification performance of protective environmental micro-surfacing materials. The results show that the prepared protective environmental functional material with tail gas purification effect was, when the molecular weight ratio of Ti: N: Fe is 1: 0.7: 0.005, the absorption peak of photocatalytic reaction is obviously red-shifted, and the absorbance is improved under visible light. The availability of photocatalytic materials is increased, and the photocatalytic performance is the optimum. When 3 % functional materials and 5 % SBR latex are used as composite modifier of emulsified asphalt, the consistency, cracking resistance and high temperature performance of composite modified emulsified asphalt are the optimum. The micro-surfacing mixture prepared with 7 % oil-stone ratio and 6 % -7 % external water has good high temperature stability, water stability and skid resistance. When the molecular weight ratio of Ti : N : Fe is 1 : 0.7 : 0.005, the HC purification efficiency reaches 12 %, the CO purification efficiency reaches 15 %, and the NOX purification efficiency reaches 30 %, which has good road performance and exhaust purification effect.