2023
DOI: 10.1039/d3ta04723g
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Tip effect assisted high active sites for oxygen evolution reaction tuned using transition metals (Cr, Fe and Mo) doped with CoP

Xiaoyun Zhang,
Shifan Zhu,
Yixue Xu
et al.

Abstract: Tip effect of the high curvature tip top can cause the electromagnetic effects to improve the catalytic performance. Transition metals (Cr, Fe and Mo) doping into CoP array nanocones alters...

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Cited by 16 publications
(5 citation statements)
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“…2d). 21 The Cl 2p spectrum could be decomposed into Cl 2p 3/2 , Cl 2p 1/2 and satellite peaks. The characteristic peaks of Cl 2p 3/2 (200.19 eV), Cl 2p 1/2 (197.67 eV) and the satellite peaks (199.29 eV) could be identified in the Cl 2p spectrum of Cl-Fe 2 P/NC (Fig.…”
Section: Resultsmentioning
confidence: 99%
“…2d). 21 The Cl 2p spectrum could be decomposed into Cl 2p 3/2 , Cl 2p 1/2 and satellite peaks. The characteristic peaks of Cl 2p 3/2 (200.19 eV), Cl 2p 1/2 (197.67 eV) and the satellite peaks (199.29 eV) could be identified in the Cl 2p spectrum of Cl-Fe 2 P/NC (Fig.…”
Section: Resultsmentioning
confidence: 99%
“…[74,75] The generalized electronic descriptor (upper-bond d band central, e W d ) is defined to illustrate the discrepancies. It can be described as Equation (10).…”
Section: Descriptors Based On Thermodynamicsmentioning
confidence: 99%
“…Transition metal-based catalysts that are expected to replace precious metals are currently hot and difficult issues in the field of OER development. [10][11][12][13][14][15][16][17] Recently, the strategies to improve the OER catalytic performance can be divided into the following categories: structure and morphology regulation, [18][19][20] vacancy and defect construction, [21][22][23][24] and surface and interface modification. [25,26] Nevertheless, the investigations on preparation strategies and catalytic mechanisms are still insufficient to support the rational design of advanced OER catalysts.…”
Section: Introductionmentioning
confidence: 99%
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“…Therefore, it is important to improve the OER performance of spinel sulfide by activating active sites and accelerating electron transmission. Many effective strategies have been carried out to enhance catalytic performance, such as dopant insertion, 5,6 defect 7,8 and heterojunction construction, 9–11 and surface interface regulation. 12,13…”
mentioning
confidence: 99%