The
high-entropy concept was applied to the synthesis of transition-metal
antimonides, M1–x
Pt
x
Sb (M = equimolar Ru, Rh, Pd, and Ir). High-entropy
antimonide samples crystallized in a pseudo-hexagonal NiAs-type crystal
structure with a P63/mmc space group were successfully synthesized through a conventional
solid-state reaction and subsequent quenching. A detailed investigation
of the composition and equilibration conditions confirmed the reversible
phase transition between a multiphase state at low temperature and
an entropy-driven single-phase solid solution at high temperatures.
Electrical resistivity, magnetization, and heat capacity measurements
of single-phase M1–x
Pt
x
Sb (x = 0.2) samples revealed a
bulk superconducting transition at 2.15(2) K. This study demonstrates
that the high-entropy concept provides numerous opportunities for
the discovery of new functional materials such as superconductors.