Electric vehicles, with their distinct power systems, weight distribution, and power control strategies compared to traditional vehicles, influence the pressure distribution in the tire contact area, thereby affecting the estimation of road adhesion coefficient. In electric vehicle research, tire adhesion coefficient serves as a measure of the frictional force between the vehicle and the road surface, directly impacting the vehicle’s handling performance. The accurate estimation of the adhesion coefficient aids drivers in better understanding the vehicle’s driving state. However, the existing brush models neglect differences in ground pressure distribution along the width direction of tires during tire camber, potentially leading to inaccuracies in adhesion coefficient estimation. This study proposes a camber brush tire model that considers the width-direction pressure distribution characteristics, aiming to enhance the accuracy of adhesion coefficient estimation under camber conditions. Experimental comparisons between the improved and original models reveal a significant enhancement in estimation precision. Consequently, the findings of this study provide valuable insights for deepening our understanding of tire camber dynamics and for designing control systems for electric vehicles, thereby improving vehicle stability and safety.