“…[1][2][3][4][5][6][7] Using neutral molecules as targets, many fundamental questions have been addressed in recent years, e. g., the localization of the core hole, [8] complex many-electron relaxation effects, [9][10][11][12] or the role of the photon momentum in the molecular dissociation process. [13,14] Molecular ions have received much less attention despite their important role as transient species in many chemical environments such as flames, [15] Earth's and Titan's ionospheres, [16,17] or interstellar gas clouds. [18,19] This is due to the fact that only much lower target densities can be prepared for targets of free charged particles as compared to what can be achieved for neutral species.…”