Titania supported dioxidotungsten(vi) complex as bio-mimic for the type II copper-containing oxidase enzyme phenoxazinone synthase

Abstract

Mononuclear dioxidotungsten(VI) complex [WVIO2(CH3-hptb)(H2O)] (1) of deferasirox (4-[3,5-bis(2-hydroxyphenyl)-1H-1,2,4-triazol-1-yl]benzoic acid, H3hptb, I) has been synthesized by the reaction of [WVIO2(acac)2] with I in MeOH and successfully characterized by various spectral techniques...