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Powder metallurgy (PM) of titanium is a potentially cost-effective alternative to conventional wrought titanium. This article examines both traditional and emerging technologies, including the production of powder, and the sintering, microstructure, and mechanical properties of PM Ti. The production methods of powder are classified into two categories: (1) powder that is produced as the product of extractive metallurgy processes, and (2) powder that is made from Ti sponge, ingot, mill products, or scrap. A new hydrogen-assisted magnesium reduction (HAMR) process is also discussed. The mechanical properties of Ti-6Al-4V produced using various PM processes are analyzed based on their dependence on unique microstructural features, oxygen content, porosity, and grain size. In particular, the fatigue properties of PM Ti-6Al-4V are examined as functions of microstructure. A hydrogen-enabled approach for microstructural engineering that can be used to produce PM Ti with wroughtlike microstructure and properties is also presented.
Powder metallurgy (PM) of titanium is a potentially cost-effective alternative to conventional wrought titanium. This article examines both traditional and emerging technologies, including the production of powder, and the sintering, microstructure, and mechanical properties of PM Ti. The production methods of powder are classified into two categories: (1) powder that is produced as the product of extractive metallurgy processes, and (2) powder that is made from Ti sponge, ingot, mill products, or scrap. A new hydrogen-assisted magnesium reduction (HAMR) process is also discussed. The mechanical properties of Ti-6Al-4V produced using various PM processes are analyzed based on their dependence on unique microstructural features, oxygen content, porosity, and grain size. In particular, the fatigue properties of PM Ti-6Al-4V are examined as functions of microstructure. A hydrogen-enabled approach for microstructural engineering that can be used to produce PM Ti with wroughtlike microstructure and properties is also presented.
The article contains sections titled: 1. Introduction 1.1. Historical Background 1.2. Economic Aspects 2. Powder Production 2.1. Mechanical Methods 2.1.1. Disintegration without Phase Change 2.1.2. Disintegration with Phase Change 2.2. Chemical Methods 2.2.1. Reduction with Solids 2.2.2. Reduction with Gases 2.2.3. Electrochemical Reduction 2.2.4. Decomposition of Gases 2.2.5. Reaction with Solids (Carbides) 2.3. Powder Characterization 2.3.1. Physical Properties 2.3.2. Chemical Properties 2.3.3. Technological Properties 2.4. Conditioning 3. Shaping Technologies 3.1. Die Compaction 3.2. Powder Forging, Extrusion, and Rolling 3.2.1. Powder Forging 3.2.2. Powder Extrusion 3.2.3. Powder Rolling 3.3. Isostatic Pressing 3.3.1. Cold Isostatic Pressing (CIP) 3.3.2. Hot Isostatic Pressing (HIP) 3.4. Injection Molding 3.5. Additive Manufacturing 4. Sintering 4.1. Sintering Mechanisms: Solid‐State Sintering 4.2. Liquid Phase Sintering 4.3. Chemical Aspects of Sintering 4.4. Sintering Practice 4.5. Sintering Atmospheres 5. Secondary and Finishing Operations 5.1. Deburring and Cleaning 5.2. Re‐pressing, Sizing, and Coining 5.3. Local Surface Densification Techniques 5.4. Machining 5.5. Joining 5.6. Surface Treatments 5.7. Heat and Thermochemical Treatments 6. Materials and Products 6.1. Precision Parts 6.1.1. Low‐Alloyed Steel Parts 6.1.2. High‐Alloyed Corrosion‐Resistant Steel Parts 6.2. Tool Steels 6.3. Electrical Contact Materials 6.3.1. Contact Materials for Low‐Voltage Switchgear 6.3.2. Contact Materials for High‐Voltage Switchgear 6.4. Magnetic Materials 6.4.1. Soft Magnets 6.4.2. Permanent Magnets 6.5. Cu and Cu Alloys 6.6. Al and Al Alloys 6.6.1. Conventional Pressed and Sintered Aluminum Alloys 6.6.2. High‐Performance Aluminum Alloys 6.7. Ti and Ti Alloys 6.8. Hardphase‐Based Materials 6.9. Refractory Metals 6.9.1. Monolithic Refractory Metals 6.9.2. Two‐Phase Refractory Metals 6.10. PM Superalloys 7. Acknowledgements
Mechanical behavior of dual-phase Ti6Al4V produced with Direct Metal Laser Sintering (DMLS) was compared to that of similar alloys produced with conventional methods (wrought and machined) and near-net-shape powder metallurgy. The elastic moduli were measured in flexure, stress-strain characteristics were measured in tensile deformation, and fatigue strengths were measured in fully reversed bending. The effect of DMLS fabrication orientation and post-processing by hot-isostatic pressure (HIP) upon mechanical behavior was studied. Both vertically and horizontally-grown DMLS Ti6Al4V materials demonstrated higher yield strength than conventional Ti6Al4V. Both HIP'd DMLS and powder metallurgy specimens displayed lower modulus and yield strength that conventional material. The fatigue strengths exhibited by DMLS materials were drastically lower than those exhibited by materials fabricated with both conventional means and powder metallurgy. These lower fatigue strengths are attributed to significantly higher surface roughness and populations of internal pores in DMLS specimens, which were ameliorated by HIP. †
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