From production to retail, the food supply chain (FSC) encompasses all stages of food production. Food is now transmitted across continents over long ranges. People depend on supply chains for basic necessities such as food, water, drinks, etc. Any disruption in these shipment pipelines poses a serious threat to human life. Supplier selection (SS) has been identified as a crucial component of FSC, which has been contemplated as a multi-criteria decision-making (MCDM) problem in many studies. The failure of some specific MCDM problems is due to failure in contemplating the relationships between alternatives under uncertain circumstances. To address such challenges, we present a contemporary method for designating green suppliers based on single-valued neutrosophic hesitant fuzzy (SVNHF) information, in which the input assessment is taken into account using single-valued neutrosophic hesitant fuzzy numbers (SVNHFNs). The foremost purpose of this analysis is to construct a topological structure on single-valued neutrosophic hesitant fuzzy sets (SVNHFSs) as well as to validate several key properties with examples. We discuss certain properties of SVNHF topology such as the SVNHF closure, SVNHF interior, SVNHF exterior, and SVNHF frontier. We also examine the conceptualization of the SVNHF dense set and SVNHF base in SVNHF topology using comprehensive examples. Eventually, to demonstrate and validate the superiority and inferiority ranking (SIR) method and choice value (CV) method in terms of their rationality and scientific basis, a real-world example of supplier selection in a food supply chain is provided. A comparative analysis is also performed to discuss the symmetry, validity and advantage of the proposed techniques.