“…With the arrival of the big data era, multiferroic materials that have more than one type of ferroic order in the same phase of one material can produce a wealth of new possibilities for data memory . These functional materials possess a wide range of applications in sensors and logical devices, such as magnetic sensors, magnetoelectric memory, and voltage-driven magnetic tunnel junctions. − They have attracted particular interest mainly because of the novel functionalities induced from the coupling/coexistence between the ferromagnetic and the ferroelectric orders. ,− Among them, ferroelectric materials always possess abundant physical properties, including piezoelectricity, pyroelectricity, second harmonic nonlinear optics, and so on. To date, the ones that shine light in investigations and utilizations are the inorganic perovskite-type oxides, such as BaTiO 3 (BTO), Pb(Zr, Ti)O 3 (PZT), and BiFeO 3 (BFO) on account of their exceptional physical performance. − Nevertheless, to address the problem of energy, environment, and biocompatibility faced by inorganic ceramics, organic small-molecular functional materials are promising supplements for inorganic counterparts due to their light weight, easy and environment-friendly processing, mechanical flexibility, low acoustic impedance, and satisfying biocompatibility. − However, the scarce discovery of organic small-molecular multiferroic materials offers limited scope for their development and further applications. , …”