Topology‐Controlled AIEE of Iminocoumarin Luminophores

Abstract

Aggregation‐induced emission enhancement (AIEE) is an unusual phenomenon where luminophores show a higher photoluminescence efficiency in the aggregated and solid state. We report the design and synthesis of a series of luminophores 1–4 with imine functionality at 6 position of coumarin and studied their AIE propensities on self‐assembly. The effect of the topology of the phenolic hydroxyl group on the emission behaviour of the luminophores has been investigated. The imines show significant solvatochromism with high emission in non‐polar solvents, whereas the emission gets quenched in the polar solvent. The fluorescence in the toluene‐hexane mixture arises due to the aggregation of fluorophores and falls under the category of AIEE. Not only the solution state emission of the isomeric iminocoumarin luminophores is notably varied, but also their solid‐state emission found to be significantly different from each other. Moreover, the iminocoumarin 1 selectively recognizes Fe(III) over Fe(II) with a prominent color change. In situ oxidation of Fe(II) with H2O2 exhibits the same effect like Fe(III) and developed a chemical combinational logic gate.

Synthesis, structure and stimulus-responsive properties of a metallogel of a designer ferrocene appended peptide mimetic

“…2b). 45 The crystals of peptide mimetic 1, suitable for X-ray diffraction analysis, were obtained from a methanol-water solution (90 : 10) by slow evaporation. Peptide mimetic 1 has two molecules in the asymmetric unit (Fig.…”