Total absolute cross sections for electron scattering on hexafluorobenzene, C 6 F 6 , and sulfur hexafluoride, SF 6 , molecules, have been measured as a function of impact energy from 0.6 to 250 eV. The total cross section for C 6 F 6 exhibits a very broad peak stretching from 10 to 100 eV with some weak features near 9.5 and 15 eV superimposed on the peak. Apart from the well-known low-energy resonant structures in the SF 6 total cross section function, a new weak resonant feature close to 25 eV has been noticed in the present experiment, in accordance with earlier theoretical calculations.