Total Vapor Pressure Measurements for 2-Ethoxyethanol with Methyl Acetate, Ethyl Acetate, Propyl Acetate, and Ethyl Propionate at 313.15 K and for 2-Ethoxyethanol with Methyl Formate at 308.15 K

Abstract

Total pressure measurements are reported for the binary mixtures of 2-ethoxyethanol with methyl acetate, ethyl acetate, propyl acetate, and ethyl propionate at 313.15 K and for 2-ethoxyethanol with methyl formate at 308.15 K. The data were obtained using a Van Ness type apparatus and were fitted to the modified Margules equation (or one of its simplified cases) using Barker's method. All mixtures show positive deviations from ideality and are represented by the model to within an average absolute deviation of approximately 0.06 kPa.

Vapor Pressures and Thermophysical Properties of Dimethoxymethane, 1,2-Dimethoxyethane, 2-Methoxyethanol, and 2-Ethoxyethanol: Data Reconciliation and Perturbed-Chain Statistical Associating Fluid Theory Modeling

“…Brown circles, Pick et al; forest green inverted triangles, Antosik et al; blue diamonds, Chylinski et al; red hexagonal stars, Antosik et al; green left-pointing triangles, DeBord et al; navy stars, Alderson et al. ; purple triangles, Chylinski et al; magenta right-pointing triangles, Pathare et al. ; forest green cross marks, Lladosa et al; brown plus signs, Cortinovis et al (partially displayed); orange open squares, Rana et al; olive asterisks, Reddy et al (partially displayed); red solid squares, this work (static); dotted lines, absolute deviations.…”

Total Vapor Pressure Measurements for 2-Ethoxyethanol with Carbon Tetrachloride, Chloroform, and Dichloromethane at 303.15 K

“…Two modifications to the apparatus described by Bhethanabotla and Campbell have been made. The pressure gauge has been replaced with one of 0.001-kPa resolution as described by Pradhan et al, 6 and the original pumps have been replaced with Ruska pumps (model 2200) having a resolution of 0.001 cm 3 . The operating ranges in temperature and pressure for the apparatus are 298-328 K and 0-133 kPa, respectively.…”

“…As part of a continuing study in this laboratory of vaporliquid equilibrium for binary mixtures containing 2-ethoxyethanol, total pressure data are reported for systems of 2-ethoxyethanol with carbon tetrachloride, chloroform, and dichloromethane. Previously, Carmona et al, 1 DeBord et al, 2 and Alderson et al 3 reported total pressure data for binary mixtures of 2-ethoxyethanol with paraffins, alcohols, and esters, respectively. We have not located any vaporliquid equilibrium data in the literature for mixtures of 2-ethoxyethanol with the chloroalkanes considered here.…”

Reply to comments of Endo and Goss concerning “development of correlations for describing solute transfer into acyclic alcohol solvents based on the Abraham model and fragment-specific equation coefficients”

“…We now include 36 experimental log K values for solutes dissolved acyclic alkoxyalcohol solvents (2-methoxyethanol, 2-ethoxyethanol, 2-propoxyethanol, 2-butoxyethanol, 2-isopropoxyethanol and 3-methoxy-1-butanol). The calculated equation coefficients given in Table 1 do not predict the 36 experimental log K values that were calculated from published solubility [6][7][8][9][10] and activity coefficient data [11][12][13][14] for solutes dissolved the fore-mentioned alkoxyalcohol solvents. (Standard error was SE = 0.504 log units for entire 2398 value data base.)…”