2017
DOI: 10.1002/app.45262
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Toward a better understanding of the emulsion polymerization of butadiene. I. Continuous conductivity measurements

Abstract: Continuous conductivity measurements were performed during the batch emulsion polymerization of butadiene along with kinetic and particle size measurements. The critical monomer conversion was obtained around 55% and the rate of polymerization was correlated to the surfactant concentration with an exponent of 0.35 which was not in agreement with the exponent offered by Smith and Ewart. In addition, the evolution of some particle‐related quantities such as particle size and number of particles during the three … Show more

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