With the development of modern technology, a variety of values and social thoughts based on streaming media have caused a huge impact on the field of ideology and culture, and contemporary college students are deeply affected. Nowadays, college students are very prone to problems such as lack of empathy, distorted values, and weakening of life values. College students commit suicide, homicide, and other illegal and criminal incidents due to unhealthy psychological reasons. This paper abstracts the emotional cognitive ability of college students into a psychological resilience model and then analyzes it. It is concluded that the overall applicability of college students to emotional cognition education in the psychological classroom is not high. In order to change the overall low applicability of this situation, this paper pioneers the application of the Internet of Things (IoT) technology to the emotional cognitive education system of college students’ psychological classrooms. Through the experiment, four results of the two psychological classroom models were obtained under different genders, different grades, different household registration types, and comprehensive conditions. The improved mode of combining the Internet of Things technology with emotional cognitive education can increase the applicability of college students to emotional cognitive education in the psychological classroom by about 6.97%. It helps to cultivate and educate the positive emotions of college students and promote the comprehensive and healthy development of college students.