Toward Efficient Hydrogen Generation Using Nickel‐Molybdenum Catalyst and Its Environmental Sustainability

Abstract

In this study, a catalyst with Ni‐Mo combination was synthesized using the electric heating/reductive tempering method. Nickel (II) nitrate hexahydrate and ammonium molybdate were combined in a ratio of 1.1 in this approach. The mixture was milled into a fine powder. It was heated to 950°C to 1000°C in a seething hood. The disappearance of green shading and emission of brownish‐yellow fumes indicated that the reaction was completed. XRD has been used to determine the crystallinity of the combined Ni‐Mo amalgam, SEM was used to investigate the surface morphology of the orchestrated Ni‐Mo compound, and inductively coupled plasma examinations were carried out to evaluate elemental percentage (%) of the integrated sample of Ni‐Mo combination. In addition, an electrical impedance analysis of as‐synthesized Ni‐Mo alloy was conducted to estimate hydrogen production in an electrochemical reaction. The electrical impedance results indicate that the synthesized Ni‐Mo catalyst exhibited an efficient charge‐transfer kinetics with a low charge‐transfer resistance (5.35 Ω). The onset potential value achieved was 18 mV with overpotential of −100 mV in IM KOH, possessing a turnover frequency of 0.91H2 s−1. These findings underscore Ni‐Mo catalyst as a promising catalyst for hydrogen generation studies. The results of this study are anticipated to be of potential significant importance in providing a cost‐effective approach towards the synthesis of Ni‐bimetallic catalyst, which in the future can serve as a promising candidate for applications involving sustainable hydrogen generation. Additionally, the proposed method's study of its greenness using the Analytical Greenness Calculator (AGREE) can help advance the usage of renewable and environmentally friendly energy sources.