This paper presents the problem of application of modern developments in the field of bio-energy for the development of autonomous mobile robots' power sources. We carried out analysis of biofuel cells, gasification and pyrolysis of biomass. Nowadays, very few technologies in the bioenergy field are conducted with regards to the demands brought by robotics. At the same time, a number of technologies, such as biofuel cells, have now already come into use as a power supply for experimental autonomous mobile robots. The general directions for research that may help to increase the efficiency of power energy sources described in the article, in case of their use in robotics, are also presented.