Arsenic (As) is abundant in the environment and can be
found in
both organic (e.g., methylated) and inorganic (e.g., arsenate and
arsenite) forms. The source of As in the environment is attributed
to both natural reactions and anthropogenic activities. As can also
be released naturally to groundwater through As-bearing minerals including
arsenopyrites, realgar, and orpiment. Similarly, agricultural and
industrial activities have elevated As levels in groundwater. High
levels of As in groundwater pose serious health risks and have been
regulated in many developed and developing countries. In particular,
the presence of inorganic forms of As in drinking water sources gained
widespread attention due to their cellular and enzyme disruption activities.
The research community has primarily focused on reviewing the natural
occurrence and mobilization of As. Yet, As originating from anthropogenic
activities, its mobility, and potential treatment techniques have
not been covered. This review summarizes the origin, geochemistry,
occurrence, mobilization, microbial interaction of natural and anthropogenic-As,
and common remediation technologies for As removal from groundwater.
In addition, As remediation methods are critically evaluated in terms
of practical applicability at drinking water treatment plants, knowledge
gaps, and future research needs. Finally, perspectives on As removal
technologies and associated implementation limitations in developing
countries and small communities are discussed.