Municipal
drinking water entering buildings can experience degraded
water quality due to in-building water treatment devices, plumbing
design, materials, and occupancy patterns. To understand water quality
patterns, we installed online sensors and collected grab samples throughout
a multistory university building to quantify temporal and spatial
fluctuations in temperature, pH, free chlorine, dissolved copper,
trihalomethanes (THMs), cellular adenosine triphosphate (cATP), and
organic matter surrogate (UV254). A whole-building water softener
had a detrimental impact on water quality, increasing pH, decreasing
disinfectant residual, and increasing THMs. Disinfectant residual
was always greatest at the building inlet, with little to no measurable
free chlorine at sinks and water fountains. Cellular adenosine triphosphate
levels were lowest at the building inlet and measured greater at water
fountains. Copper levels were <0.2 mg/L entering the building but
ranged from 0.5 to 1.5 mg/L within the building. HVAC operations resulted
in less variability for in-building water temperature than at the
water treatment plant with temperatures averaging 5 °C warmer
inside the building than at the building inlet. Trihalomethane concentrations
were influenced by chlorine residual, pH, and water demand, with consistently
higher in-building measurements than at the building inlet. Trihalomethane
speciation remained constant throughout the study with chloroform
being the greatest contributor to speciation, followed by dichlorobromoform,
dibromochloromethane, and finally bromoform.