a b s t r a c tDistributions and magnitude of metals in water, sediment and soil collected from the watershed and estuarine areas of southern Bohai Sea, were investigated. The largest dissolved concentrations of As, Cu and Zn in water were 347.70, 2755.00, 2076.00 lg/L, respectively, much higher than corresponding drinking water guidelines. The greatest concentrations of Cu, Zn, Cr, Ni, Pb, As and Cd in sediments were 1462.2, 1602.17, 196.43, 67.15, 63.54, 73.86 and 1.41 mg/kg, dw, respectively. The mean concentrations of Cu, Ni, Cd, Zn, Cr, Pb and As in soils were 24.67, 24.73, 0.14, 64.75, 56.52, 25.12 and 9.34 mg/kg, dw, respectively. Land use was confirmed to be an important factor of influence on soil metal concentrations. Metal contents along the watershed of Jie River were significantly greater than in other locations. The detection of metals in relatively high concentrations from different environmental matrices in this region indicates the necessity of further studies.Ó 2013 Elsevier Ltd. All rights reserved.In the past few decades, metals contamination in the environment has been attracting increasing concern around the world due to their toxicity, persistence and bioaccumulation characteristics (Cheng, 2003;Davis and Atkins, 2001). Unlike organic pollutants which can be degraded to less harmful components by biological or chemical processes, metals are considered as not naturally decomposable. The environmental metal concentrations are influenced by both natural and anthropogenic factors including parent materials, industrial and domestic sewage discharges, mining, smelting, e-wastes recycling (Xu et al., 2011). China is currently the worlds' second largest economy as a result of rapid industrial development over the past few decades. However, this rapid economic growth has been accompanied by considerable environmental side effects, especially pollution by metals. Coastal and estuarine areas are among the most important places for human inhabitants, yet they are often the ultimate receptacles of pollutants (Pan and Wang, 2012). The distribution and contamination levels of metals in the watershed, estuaries, coastal, bay and sea environments in China have been extensively investigated (Gao and Chen, 2012;Ip et al., 2007;Zhang et al., 2009).The Bohai Sea is a nearly enclosed interior sea located in northeast China and consists of Liaodong Bay, Bohai Bay, Laizhou Bay, and the middle sea (Meng et al., 2008). Due to intensive urbanization and industrialization, Bohai Sea and nearby coastal areas and estuaries have severe metal pollution problems (Wang et al., 2011b). Particularly, its proximity to Beijing, the capital of China, makes it one of the busiest seaways in the world . Large amounts of metals are carried into this sea through either direct discharges or loads from rivers, such as the Yellow River, Liaohe River and Xiaoqing River. For example, the Liaohe River discharged 390 t of metals into the sea in 2002, and the Yellow River totally discharged 200 t of metals in 2003 (Wang andWang, 2007). The...