“…As a result of the effective porosity in Hillvi, mass remains longer in the unsaturated and saturated stores of each grid cell, because a fraction (1 − * n eff ) of these stores (immobile soil water) does not take part in the transport process. While a simplification, because it, for example, ignores exchange between the mobile and immobile domain, this parameter represents a dual porosity system (e.g., Buttle and Sami, 1990;Corapcioglu and Wang, 1999;Stephens et al, 1998;Rasmussen et al, 2000) with a mobile and immobile water domain and the calibration result for this parameter suggests that the mixing volume of deuterium was controlled by an immobile soil water fraction. A dual porosity system is consistent with the study of Brooks et al (2010) in the same small watershed: based on water-isotope data, they found soil water that is tightly bound (immobile) within small soil pores remains in the soil or leaves the soil through transpiration by trees, but it does not contribute to matrix flow and is disconnected from mobile or stream water.…”