Tracing Pb Pollution Penetration in Temperate Podzols

Abstract

We combine high‐resolution soil sampling with lead (Pb) analyses (concentrations and stable isotopes) in two temperate podzols, together with previous data obtained with selective Al and Fe dissolution techniques. We aim to assess how atmospheric Pb is incorporated into the soils during pedogenesis. Partial least squares modelling for Pb concentrations shows that the podzolization process has the largest effect on Pb concentration (80·3% of the variance). The proportion of inorganic secondary compounds, the input of fresh organic matter from the soil surface and the relative abundance of Fe versus Al are responsible for a small part of the Pb concentration variance. Lead isotopic composition (206Pb/207Pb ratios) depends on soil organic matter content either fresh/poorly humified (57·3% of the variance) or humified (24·7% of the variance). The Pb linked to inorganic compounds and the overall podzolization process play a minor role in isotopic signature (5·3 and 3·7% of the variance respectively). Soil pH appears to be the controlling variable of the different transport and retention mechanisms. The relatively low isotopic ratios observed in spodic horizons result from geogenic Pb released through the preferential dissolution of the isotopically distinct most weatherable minerals of the parent material in the eluvial horizons, which undergoes downward mobilization. An accurate knowledge of soil reactive components and formation mechanisms is essential to a correct diagnose of the scope of Pb pollution and a more effective design of remediation strategies. Copyright © 2017 John Wiley & Sons, Ltd.

Catchment Runoff in Industrial Areas Exports Legacy Pollutant Zinc from the Topsoil Rather than Geogenic Zn

“…We hypothesized that the behavior of Zn and Pb in polluted forest ecosystems is similar in several aspects. For Zn, we tested two hypotheses that were previously validated for Pb: − (i) legacy atmospheric Zn is temporarily stored in the organic horizon, and (ii) headwater catchments slowly “bleed” pollutant Zn rather than the abundant but slowly mobilized geogenic Zn.…”