Purpose -This paper investigates the impacts of institutional quality in exporting and importing countries on agro-food exports from the world's leading emerging economies:Brazil, the Russian Federation, India, and China (BRIC countries).Design/methodology/approach -Measuring is based on using the gravity trade model and econometric panel data analysis for the period 1998-2009.Findings -Agro-food export from the BRIC countries has increased particularly by Brazil and China. The Russian Federation has experienced stagnating and volatile patterns. Brazil and India have strengthened market shares on the existing importing markets, while the Russian Federation has experienced severe deterioration. Export of existing products is more important than of new products. Agro-food export is positively associated with institutional quality in exporting and importing countries, gross domestic product and population sizes in importing countries, but negatively with distance.Research limitations/implications -Among institutional quality variables, the focus is on indices of legal structure and security of property rights and freedom to trade internationally in agro-food importing countries and the BRIC exporting countries.Practical implications -Different institutions and their quality affect agro-food exports differently. The impact of institutions is not uniform across product groups.Originality/value -This paper adds the impacts of institutional quality on agro-food exports.Except for processed products for final household consumption, agro-food export from the BRIC countries is positively associated with freedom to trade internationally and quality of legal system as institutional quality in exporting and importing countries.