The five-bar linkage, used in the form of a planar manipulator, benefits from easy controllability and relatively simple kinematic structures, which mean that it can be used in several applications in robotics, rehabilitation, and haptic devices, etc. This paper proposes an optimal synthesis method for a symmetrical five-bar linkage of type 5-RRRRR, with a singularity-free dexterous workspace, based on workspaces with predefined shapes, like squares, rectangles, triangles, circles, and ellipses. The synthesis conditions, to avoid singularities, are given as inequations, which can be further substituted with a system of equations, by introducing the supraunitary coefficient, k. The analytical solutions of the resulting system of equations enable the computation of the link lengths of the five-bar linkage. The optimization method provides the optimal value of the supraunitary coefficient, in order to obtain a maximum value for the minimum input transmission angle and a minimum value for the manipulator size. In this paper, the authors present an analytical approach to the optimal synthesis of a symmetrical five-bar linkage for different shapes of workspace, with the same surface and coordinates in terms of the mass center, as well as the resulting link lengths. In regard to the numerical examples, the authors considered and compared performance indices, such as manipulability, the condition number, and stiffness. The considered examples showed that an equilateral triangle-shaped workspace achieved higher global manipulability, a square-shaped workspace achieved higher global dexterity and the minimum input transmission angle, and circular workspaces achieved the highest mean stiffness and total surface size. It was observed that the synthesis method generates structures that are well-suited to singularity-free dexterous workspaces, with nonzero stiffness values.