2024
DOI: 10.1007/s10847-024-01228-2
|View full text |Cite
|
Sign up to set email alerts
|

Trans-to-cis isomerization of a platinum(II) complex with two triphosphine ligands via coordination with gold(I) ions

Kazuki Nagasato,
Taichi Baba,
Hayato Soma
et al.

Abstract: The reaction of a square-planar platinum(II) complex containing two bis(2-diphenylphosphinoethyl)phenylphosphine (triphos), [Pt(triphos)2](NO3)2, with [Au(tu)2]Cl (tu = thiourea) gave a new trinuclear AuI2PtII complex, [Pt(triphos)2{Au(tu)}2]Cl2(NO3)2, through Au-P coordination. While the [Pt(triphos)2]2+ unit in [Pt(triphos)2](NO3)2 adopted the trans-meso configuration, only the cis-racemic isomer was observed for [Pt(triphos)2{Au(tu)}2]Cl2(NO3)2. 31P NMR spectroscopy indicated rapid equilibrium among the pos… Show more

Help me understand this report
View preprint versions

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Publication Types

Select...

Relationship

0
0

Authors

Journals

citations
Cited by 0 publications
references
References 36 publications
0
0
0
Order By: Relevance

No citations

Set email alert for when this publication receives citations?