Abstract. Safe and reliable transport of dense CO 2 by pipes needs a careful choice of the constitutive pipe materials to prevent brittle crack propagation after ductile or brittle failure initiation. This unexpected phenomenon can occur after failure or leak promoted by external interferences. In this case, the rapid decompression of dense CO 2 into gas leads to a very low local temperature of about -80°C. To prevent risk of brittle fracture initiation and propagation, the material must remain ductile at this temperature. In other terms, its ductile-brittle transition temperature (DBTT) has to be lower than -80°C minus a margin. It is admitted that the DBTT is not a material characteristic but depends on specimen geometry, loading rate and loading mode, i.e. on constraints. A loss in constraint leads to a lower brittle-ductile transition temperature. In order to select a steel for transportation of dense CO 2 , transition temperatures T t (from tensile test), T K27 and T K50 (from Charpy test) and T K100 (from fracture mechanics test) have been determined on an API 5L X65 pipeline steel. These transition temperatures have been reported versus a constraint parameter, e.g. T-stress, in a master curve. Differences between different brittle-ductile transition temperatures and temperature corresponding to T-stress acting in a pipe submitted to internal pressure on the master curve, give an estimation of the conservatism of the chosen reference transition temperature.