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Recent technological developments need lightweight materials with high mechanical properties, especially in energy, automotive, and aerospace industries. [1,2] New chemical compositions have been developed with the increased demand for Al and their alloys. Moreover, to increase their mechanical properties, thermomechanical processes, such as extrusion, upsetting, and wire drawing, have widely been used for industrial applications of Al and its alloys. Severe plastic deformation (SPD) is one of the thermomechanical processes, which increases dislocation density. This increase results in finer grain sizes and increased mechanical properties, which render SPD techniques an attractive method. [3,4] Conventional methods, such as extrusion or upset forging, are able to deform, generally, external parts of materials. However, SPD methods, such as equal channel angular pressing (ECAP), can produce more homogenous strain distribution along the cross section of the material due to homogenous severe deformation. SPD methods are capable of doubling the mechanical strength while manufacturing ultrafine grain structures with mean grain sizes smaller than 400 nm. [4-6] Despite improved material properties' results of SPD techniques, most of them are still being used at the laboratory scale due to their manufacturing costs and usage difficulties. Materials size and length are the usage difficulties, which is generally restricted by die sizes. According to the literature, the ECAP is more convenient for producing longer specimens than other SPD methods for producing longer size ultrafine-grained materials. [7,8] However, this technique restricts the specimen length with its die size and plunger length, which is a significant limitation. High friction rate between the die walls and the specimen is another restriction for specimen size. Movable side walls during ECAP are developed as a solution to friction. However, the specimen length is limited to the die size. [9] Conform methods adapt continuous material feeding to SPD processes, which allow manufacturing fine-grained longer products. The conform SPD application was developed by Raab et al. in 2004 [10] for deformation of pure Al with ECAP. Various materials were used in conform methods, such as Ti G4, [11] TiNi, [12] Al6061, [13] and Al6101. [14] The most significant limitation of this method is the high friction rate between die and material. Especially, materials with low melting temperatures are effected from friction heat and result with a grain recovery that also decreases process efficiency. In the incremental ECAP (I-ECAP) process, which was first described in 2007, the material is fed step by step, and a punch deforms material between these steps; there are two separated synchronous movements of punch (deformation) and feeding system. [15] Thus, there is not a load on the specimen during feeding, which also eliminates high friction rates between die and specimen in contrast with traditional ECAP. Because of the continuous feeding of materials in the I-ECAP method, the ...
Recent technological developments need lightweight materials with high mechanical properties, especially in energy, automotive, and aerospace industries. [1,2] New chemical compositions have been developed with the increased demand for Al and their alloys. Moreover, to increase their mechanical properties, thermomechanical processes, such as extrusion, upsetting, and wire drawing, have widely been used for industrial applications of Al and its alloys. Severe plastic deformation (SPD) is one of the thermomechanical processes, which increases dislocation density. This increase results in finer grain sizes and increased mechanical properties, which render SPD techniques an attractive method. [3,4] Conventional methods, such as extrusion or upset forging, are able to deform, generally, external parts of materials. However, SPD methods, such as equal channel angular pressing (ECAP), can produce more homogenous strain distribution along the cross section of the material due to homogenous severe deformation. SPD methods are capable of doubling the mechanical strength while manufacturing ultrafine grain structures with mean grain sizes smaller than 400 nm. [4-6] Despite improved material properties' results of SPD techniques, most of them are still being used at the laboratory scale due to their manufacturing costs and usage difficulties. Materials size and length are the usage difficulties, which is generally restricted by die sizes. According to the literature, the ECAP is more convenient for producing longer specimens than other SPD methods for producing longer size ultrafine-grained materials. [7,8] However, this technique restricts the specimen length with its die size and plunger length, which is a significant limitation. High friction rate between the die walls and the specimen is another restriction for specimen size. Movable side walls during ECAP are developed as a solution to friction. However, the specimen length is limited to the die size. [9] Conform methods adapt continuous material feeding to SPD processes, which allow manufacturing fine-grained longer products. The conform SPD application was developed by Raab et al. in 2004 [10] for deformation of pure Al with ECAP. Various materials were used in conform methods, such as Ti G4, [11] TiNi, [12] Al6061, [13] and Al6101. [14] The most significant limitation of this method is the high friction rate between die and material. Especially, materials with low melting temperatures are effected from friction heat and result with a grain recovery that also decreases process efficiency. In the incremental ECAP (I-ECAP) process, which was first described in 2007, the material is fed step by step, and a punch deforms material between these steps; there are two separated synchronous movements of punch (deformation) and feeding system. [15] Thus, there is not a load on the specimen during feeding, which also eliminates high friction rates between die and specimen in contrast with traditional ECAP. Because of the continuous feeding of materials in the I-ECAP method, the ...
This manuscript has provided an overview of the development of TiNi alloys and their applications in biomedicine. The microstructures and properties of TiNi alloys are first introduced. The breakthroughs in the manufacturing and applications in biomedicine of TiNi alloys in recent years have been achieved by scientists and are presented in the present paper. It is well known that the properties of TiNi alloys are affected by the modification methods on the surface of bulk TiNi alloys. The main preparation technologies of TiNi alloy coatings are evaluated, with particular attention to several spray technologies. Then, the biocompatibility, strong anticorrosion and antiwear properties, and mechanism of TiNi alloys are also described in detail. Several advanced manufacturing processes of TiNi alloys are also briefly outlined such as selective laser melting and spark plasma sintering. The performance of TiNi alloy coatings prepared by thermal spraying techniques are fully qualified for medical applications. Thermal spraying techniques have great prospects in reducing the cost and improving the quality of TiNi alloy medical products.
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