Transition Metal‐Catalyzed C–H Functionalization of Indole Benzenoid Ring

Kumar, Vikash; Maayuri, Rajaram; Mantry, and Lusina; Gandeepan, Parthasarathy

doi:10.1002/9781119774167.ch4

Transition‐Metal‐Catalyzed C‐H Functionalization of Heterocycles 2023

DOI: 10.1002/9781119774167.ch4

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Transition Metal‐Catalyzed C–H Functionalization of Indole Benzenoid Ring

Vikash Kumar¹,

Rajaram Maayuri²,

and Lusina Mantry³

et al.

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2024

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Ruthenium (II)‐Catalysed Regioselective C6 Alkylation of Indoles with Maleimides

Jadhav,

Dawande

2024

Adv Synth Catal

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Ruthenium (II)‐catalysed regioselective C6 alkylation of indole‐7‐carboxamides with maleimide has been described. Electronically diverse maleimides reacted with various indoles to furnish corresponding C6 substituted succinimide derivatives of indoles with 46–89% yields. The reaction shows functional group tolerance. The synthetic utility of the reaction has been demonstrated through the conversion of the obtained product to the corresponding hexahydropyridazinyl derivative. We also studied the kinetics of the reaction through intermolecular competitive experiments with electronically distinct indole‐7‐carboxamides.

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Ruthenium (II)‐Catalysed Regioselective C6 Alkylation of Indoles with Maleimides

Jadhav,

Dawande

2024

Adv Synth Catal

View full text Add to dashboard Cite

show abstract

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Transition Metal‐Catalyzed C–H Functionalization of Indole Benzenoid Ring

Cited by 1 publication

References 72 publications

Ruthenium (II)‐Catalysed Regioselective C6 Alkylation of Indoles with Maleimides

Ruthenium (II)‐Catalysed Regioselective C6 Alkylation of Indoles with Maleimides

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