2024
DOI: 10.1021/jacsau.4c00500
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Transition-Metal-Free C-Diarylations to Reach All-Carbon Quaternary Centers

Shobhan Mondal,
Benjamin Gunschera,
Berit Olofsson

Abstract: Herein, we disclose a convenient protocol for the αdiarylation of carbon nucleophiles to yield heavily functionalized quaternary products. Diaryliodonium salts are utilized to transfer both aryl groups under transition-metal-free conditions, which enables an atom-efficient and high-yielding method with broad functional group tolerance. The methodology is amenable to a wide variety of carbon nucleophiles and can be utilized in late-stage functionalization of complex arenes. Furthermore, it is compatible with a … Show more

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