2004
DOI: 10.1002/ejic.200400110
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Transition Metal Ion Directed Self‐Assembly of Polynuclear Coordination Complexes: Structural Characterization and Magnetic Properties

Abstract: The reactions of different transition metals with the multidentate ligand N, 3, (5); and the trinuclear complex [{Fe 3 (OH)(btapca) 3 }·2DMF·2MeOH] (6). The dominant characteristic of these polynuclear complexes is that there are µ 3 -or µ 4 -oxygen atoms in the metal polyhedrons. The hexanuclear complexes 1 and 2 show similar octahedral features

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Cited by 34 publications
(11 citation statements)
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“…is 3.294 Å, which is shorter than those of the mono-phenoxy bridged dinuclear copper(II) complexes [ (2) In our previous paper, we have reported a Ni(II)-btapca pentanuclear complex [{Ni 5 (OH) 2 (btapca) 4 }Á4DMFÁMeOH] [4]. Though the prepare processes are very similar, the result displays significant difference.…”
Section: Resultscontrasting
confidence: 57%
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“…is 3.294 Å, which is shorter than those of the mono-phenoxy bridged dinuclear copper(II) complexes [ (2) In our previous paper, we have reported a Ni(II)-btapca pentanuclear complex [{Ni 5 (OH) 2 (btapca) 4 }Á4DMFÁMeOH] [4]. Though the prepare processes are very similar, the result displays significant difference.…”
Section: Resultscontrasting
confidence: 57%
“…[25]. But their structures all have some differences from the tetrameric Ni(II) complex { [Ni 4 ((l 2 -O 2 H) 2 (btapca) 4 )]Á DMFÁMeOHÁ3.5H 2 O} reported in this paper.…”
Section: Resultscontrasting
confidence: 54%
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