Transition metal oxides for sodium-ion batteries

Su, Heng; Saddique, Jaffer; Yu, Haijun

doi:10.1016/j.ensm.2016.06.005

Cited by 283 publications

(152 citation statements)

References 119 publications

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“…Due to these reasons it is vital to search for stable anode materials, and transition metal oxides (TMOs) have been considered as an alternative electrodes in Li-/Naion battery technology because of their higher reversible capacities along with safer operating potentials [32,33]. Among the TMOs, the vanadium based oxides have been extensively studied as anode and cathode for both Li and Na-ion batteries, where various oxidation state of vanadium ranging from +5 to +2 have been utilized [34][35][36][37][38].…”

Section: Introductionmentioning

confidence: 99%

Diffusion coefficient and electrochemical performance of NaVO3 anode in Li/Na batteries

Chandra

Khan

Shukla

et al. 2020

Electrochimica Acta

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We study Na ion diffusion and electrochemical performance of NaVO3 (NVO) as anode material in Li/Na-ion batteries with the specific capacity of ≈350 mAhg −1 at the current density 11 mAg −1 after 300 cycles. Remarkably, the capacity retains ≥200 mAhg −1 even after 400 cycles at 44 mAg −1 with Coulombic efficiency >99%. The deduced diffusion coefficient from galvanostatic intermittent titration technique (GITT), electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) measurements for NVO as anode in Li-ion battery is in the range of 10 −10 -10 −12 cm 2 s −1 . In case of Na-ion batteries, the NVO electrode exhibits initial capacity of 385 mAhg −1 at 7 mAg −1 current rate, but the capacity degradation is relatively faster in subsequent cycles. We find the diffusion coefficient of NVO-Na cells similar to that of NVO-Li. On the other hand, our charge discharge measurements suggest that the overall performance of NVO anode is better in Li-ion battery than Na-ion. Moreover, we use the density functional theory to simulate the energetics of Na vacancy formation in the bulk of the NVO structure, which is found to be 0.88 eV higher than that of the most stable (100) surface. Thus, the Na ion incorporation at the surface of the electrode material is more facile compared to the bulk.

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Section: Introductionmentioning

confidence: 99%

Diffusion coefficient and electrochemical performance of NaVO3 anode in Li/Na batteries

Chandra

Khan

Shukla

et al. 2020

Electrochimica Acta

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“…However, issues such as insufficient Li reserves and the corresponding increase in cost have made the search for other low‐cost batteries inevitable . Recently, Na‐ion batteries have emerged as an alternative to Li‐ion batteries because of the crustal abundance and low price of Na . The similarities in the underlying electrochemical mechanisms between Na‐ion and Li‐ion batteries have driven intensive studies on the development of appropriate Na‐ion storage materials .…”

Section: Figurementioning

confidence: 99%

Cellulose‐Templated, Dual‐Carbonized Na₃V₂(PO₄)₃ for Energy Storage with High Rate Capability

Sohn

Son

et al. 2018

ChemElectroChem

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Sodium‐ion rechargeable batteries are a promising candidate for large‐scale electrical energy storage systems, owing to the abundance of sodium resources. Herein, we report the development of carbon‐incorporated NASICON‐Na3V2(PO4)3 (NVP) as an active cathode material for Na‐ion batteries, using carboxymethyl cellulose (CMC) and sucrose as dual carbon sources. The interaction between CMC and sucrose resulted in the formation of a highly porous structure (surface area: 58.998 m2 g−1) with increased sp2 carbon species, facilitating mass and charge transportation. The specific capacity (104.99 mAh g−1) of dual‐carbonized CMC/sucrose‐NVP (CS‐NVP) was close to the theoretical capacity (117.6 mAh g−1). Furthermore, dual‐carbonized NVP exhibited stable cyclability, showing a specific capacity of 75.04 mA g−1 even at a high rate of 20 C.

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“…Graphene oxide is known to be a good 2D support to nucleate and anchor metal oxide nanoparticles on the edges and surface which has been backed up recently . Transition metal oxides such as MnO 2 , Fe 2 O 3 etc have received attention across the world and are also regarded as promising electrode materials of lithium or sodium ion batteries in relation to energy storage and ability to deliver reversible capacity . These oxides when in hybrid with other nanostructured materials of different shapes give rise to high surface zone, non‐poisonous quality, biocompatibility, simplicity of manufacture, and also astounding electrochemical reactant movement.…”

Section: Introductionmentioning

confidence: 99%

Thermal Analysis, Morphology and Electrochemical Application of Graphene Decorated SnO₂ Nanoparticles

Elemike

Maumau

Onwudiwe

2019

Macromolecular Symposia

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In this present investigation, reduced graphene oxide (rGO)–SnO2 nanocomposites were synthesized via hydrothermal and microwave methods. The nanocomposites were characterized using Fourier transform infrared spectra (FTIR), Scanning electron microscopy (SEM), Thermogravimetric analysis (TGA), and cyclic voltammetric (CV) methods.The SEM images demonstrated different morphologies and the TGA equally showed different thermal behavior of the nanocomposites. Some conditions such as concentrations and synthetic procedures were varied in order to optimize the nanocomposites formulation and devise the means for excellent product applications. The results of the research showed that the nanocomposites have higher activity under microwave assisted conditions.

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Transition metal oxides for sodium-ion batteries

Cited by 283 publications

References 119 publications

Diffusion coefficient and electrochemical performance of NaVO3 anode in Li/Na batteries

Diffusion coefficient and electrochemical performance of NaVO3 anode in Li/Na batteries

Cellulose‐Templated, Dual‐Carbonized Na₃V₂(PO₄)₃ for Energy Storage with High Rate Capability

Thermal Analysis, Morphology and Electrochemical Application of Graphene Decorated SnO₂ Nanoparticles

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Transition metal oxides for sodium-ion batteries

Cited by 283 publications

References 119 publications

Diffusion coefficient and electrochemical performance of NaVO3 anode in Li/Na batteries

Diffusion coefficient and electrochemical performance of NaVO3 anode in Li/Na batteries

Cellulose‐Templated, Dual‐Carbonized Na3V2(PO4)3 for Energy Storage with High Rate Capability

Thermal Analysis, Morphology and Electrochemical Application of Graphene Decorated SnO2 Nanoparticles

Contact Info

Product

Resources

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Cellulose‐Templated, Dual‐Carbonized Na₃V₂(PO₄)₃ for Energy Storage with High Rate Capability

Thermal Analysis, Morphology and Electrochemical Application of Graphene Decorated SnO₂ Nanoparticles