Transition metals in organic synthesis Annual survey covering the year 1987

Hegedus, Louis S.

doi:10.1016/0022-328x(89)87343-7

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“…Some important recent reviews include: organoiron chemistry [ 569 , 570 ], transition metals in organic synthesis [ 571 , 572 ], transition metals in organic synthesis: hydroformylation, reduction and oxidation [ 573 ], and the use of iron (in addition to other transition metals) complexes as catalysts for alkene epoxidation [ 574 ].…”

Section: Miscellaneous Recent Resultsmentioning

confidence: 99%

New chemical and stereochemical applications of organoiron complexes

Fatiadi

1991

J. RES. NATL. INST. STAN.

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The objective of this review is to provide a current overview of the rapidly developing chemistry of organometallic complexes and particularly organoiron complexes useful in asymmetric and stereoselective reactions. Also covered are stereoselective reactions of α, β-unsaturated acyl ligands bound to the chiral auxiliary [(η5-C5H5) Fe(CO)(PPh3)] and new applications of organoiron complexes in the synthesis of natural products. The mechanistic aspects and stabilizing effects of the Fe(CO)3 group for alkenes or conjugated dienes are discussed. A brief summary of recent work on the special role of iron in biological reactions is also included.

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