1999
DOI: 10.1063/1.480064
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Transition probabilities and electronic transition moments of the A 2Σ+–X 2Π and D 2Σ+–X 2Π systems of nitric oxide

Abstract: Dispersed fluorescence scans of the A–X(4,v″) and D–X(0,v″) progressions of nitric oxide, after two-photon excitation, are used to determine the electronic transition moments of these band systems. The measured collision free lifetimes of 206±7 ns for A 2Σ+, v′=0, and 18±1 ns for D 2Σ+, v′=0 are used to place transition probabilities on an absolute basis. The branching ratio for D→X is 3.0±0.3 times that for D→A and more than 30 times that for D→C. The ratio of two-photon absorption cross sections for D–X(0,0)… Show more

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Cited by 205 publications
(217 citation statements)
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References 66 publications
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“…For the CN-blue, NH, and OH-blue systems, the line lists by Kurucz (1993) were adopted, as implemented in Castilho et al (1999). For the CH blue systems, the LIFBASE program of Luque & Crosley (1999) was used. The OH vibration-rotation line list is the one implemented in Meléndez et al (2001).…”
Section: Molecular Line Opacitiesmentioning
confidence: 99%
“…For the CN-blue, NH, and OH-blue systems, the line lists by Kurucz (1993) were adopted, as implemented in Castilho et al (1999). For the CH blue systems, the LIFBASE program of Luque & Crosley (1999) was used. The OH vibration-rotation line list is the one implemented in Meléndez et al (2001).…”
Section: Molecular Line Opacitiesmentioning
confidence: 99%
“…For each element X, Col. 2 gives the mean abundance log (X) = log N X /N H + 12, Col. 3 the number of lines measured, Col. 4 the standard deviation of the results, and Cols. 5 and 6 [X/H] and [X/Fe], respectively (where program of Luque & Crosley (1999) was used to compute line positions and g f -values. Excitation energies and isotopic shifts were taken from the line list of Jörgensen et al (1996), as LIFBASE only provides line positions for 12 CH.…”
Section: Carbon and Nitrogenmentioning
confidence: 99%
“…The assignment of the spectral peaks is based on the LIFBASE database. 34 The P 1 (1) and Q 1 (1) (and Q 21 (1)) transitions originating from the J ′′ = 3/2 rotational ground state and P 1 (2) (and P 21 (2)) and Q 1 (2) (and Q 21 (2)) of the first rotational excited J ′′ = 5/2 are clearly resolved. Since our dye laser has a bandwidth of about 0.1 cm -1 , the lines Q 1 (1) and Q 21 (1), P 1 (2) and P 21 (2), and Q 1 (2) and Q 21 (2) are overlapped and not resolvable.…”
Section: Rotational State Populationsmentioning
confidence: 96%