bands of 20 Ne are investigated with microscopic structure and reaction calculations via proton and α inelastic scattering off 20 Ne. Structures of 20 Ne are calculated with variation after parity and total angular momentum projections in the antisymmetrized molecular dynamics(AMD). The K π = 0 + 1 and K π = 0 − 1 bands have 16 O + α cluster structures, whereas the K π = 2 − band shows a 12 C + 2α-like structure. Microscopic coupled-channel calculations of proton and α scattering off 20 Ne are performed by using the proton-nucleus and α-nucleus potentials, which are derived by folding the Melbourne g-matrix N N interaction with AMD densities of 20 Ne. The calculation reasonably reproduces the observed cross sections of proton scattering at Ep = 25-35 MeV and α scattering at Eα = 104-386 MeV. Transition properties from the ground to excited states are discussed by reaction analyses of proton and α inelastic processes. Mixing of the K π = 2 − and K π = 0 − 1 bands is discussed by detailed analysis of the 0 + 1 → 3 − 1 and 0 + 1 → 3 − 2 transitions. For the 3 − 1 state, mixing of the K π = 0 − 1 cluster component in the K π = 2 − band plays an important role in the transition properties.