Transition state dynamics of F + ICl, C<sub>2</sub>H<sub>5</sub>I reactive scattering

Jarvis, R.D.; White, R.W.P.; Zhu, Z. Z.; Smith, David J.; Grice, R.

doi:10.1080/00268979200100421

Cited by 7 publications

(1 citation statement)

References 23 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The late Roger Grice's group in Manchester carried out a great deal of work on a variety of F, Cl, and O( 3 P) reactions (217)(218)(219)(220)(221), as well as some studies of radical reactions such as CH 3 + I 2 (185) and OD + Br 2 (222). A new CMB apparatus has been built at Cornell, and studies of transition metal reaction dynamics have been ?…”

Section: Polyatomic Reactionsmentioning

confidence: 99%

CROSSED-BEAM STUDIES OF REACTION DYNAMICS

Casavecchia

Balucani²,

Volpi³

1999

Annu. Rev. Phys. Chem.

106

View full text Add to dashboard Cite

This article reviews recent progress in our understanding of gas-phase neutral reaction dynamics as made possible by improvements in the crossed molecular beam scattering technique for measuring reactive differential cross sections. A selection of crossed-beam studies on systems that play a fundamental role in our basic understanding of reaction phenomena are discussed to illustrate the capabilities of the experimental method. The examples include benchmark atom-diatom abstraction and insertion reactions, and four-atom radical reactions for which state-to-state, state-resolved, or state-averaged differential cross sections have recently been measured. The results are discussed in the light of the latest related theoretical developments regarding the treatment of potential energy surfaces and the dynamics of the systems. Recent results on crossed-beam studies of chemically relevant reactions of carbon, nitrogen, and oxygen atoms are also reviewed, and the latest developments in the technique are noted.

show abstract