Transport of penetrants in polymeric materials

Abstract

Transport phenomena of chemical species in polymers underpin many applications. This mini‐review discusses several key transport scenarios in polymer gels, melts and crosslinked polymer networks. Transport mechanisms of a wide variety of penetrant and polymer chemistries are discussed via activated hopping theory and cover across the rubbery, intermediate/deeply supercooled and glassy states of polymers. Moreover, we also discuss the ionic conductivity in polymer electrolytes, emphasizing the relationship between ion diffusion and the segmental relaxation of polymers and highlighting current challenges in the community. Finally, potential research directions are suggested concerning how external fields, such as mechanical force fields, active matter and self‐propelling particles, affect the particle transport in polymers. This mini‐review offers a general overview of motivations for studying penetrant transports in polymers and diverse mechanisms involved. © 2024 Society of Chemical Industry.