2004
DOI: 10.1023/b:ruel.0000046487.55515.a9
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Transport Properties of Solid Electrolytes: Effect of the Isotope Composition of Lithium Charge Carriers

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Cited by 3 publications
(5 citation statements)
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“…In addition, all of the explored ternary chlorides have a room-temperature conductivity of >10 –4 S/cm, a promising trend for the family of our new compounds. The only candidate presented for LLXO systems, Li 5 SiN 3 , has previously been investigated as both a cathode and solid-electrolyte material. , This is exciting as the material is synthesizable and able to be assembled into a test cell.…”
Section: Discussionmentioning
confidence: 99%
See 1 more Smart Citation
“…In addition, all of the explored ternary chlorides have a room-temperature conductivity of >10 –4 S/cm, a promising trend for the family of our new compounds. The only candidate presented for LLXO systems, Li 5 SiN 3 , has previously been investigated as both a cathode and solid-electrolyte material. , This is exciting as the material is synthesizable and able to be assembled into a test cell.…”
Section: Discussionmentioning
confidence: 99%
“…The only candidate presented for LLXO systems, Li 5 SiN 3 , has previously been investigated as both a cathode and solid-electrolyte material. 51 , 52 This is exciting as the material is synthesizable and able to be assembled into a test cell.…”
Section: Discussionmentioning
confidence: 99%
“…Several studies have investigated the effects of isotopic substitution on the magnitude of ionic transport in Li + conducting borate glasses, [37][38][39][40] but, in general, there are not many studies of isotope effects in solid-state Li + battery materials. [41][42][43] In the study of reaction kinetics, it is commonly the ratio of the reaction rate constants that is used to quantify the isotope effect. 31,44 In that case, constant factors cancel out by taking the ratio.…”
Section: Spin Alignment Echo (Sae) This Measurement Technique Assesse...mentioning
confidence: 99%
“…Such a complex unit cell is known to be beneficial for lowering the thermal conductivity of the materials. , The cubic phase with high symmetry, as stabilized by introducing the dilute element, leads to high band degeneracy and large Seebeck coefficient . The tuning effects of the dilute elements on both electrical and thermal properties render the DECs ideal materials for thermoelectric applications. Some DECs found in our search are Li- or Na-rich, e.g., Li 6 (Mo/W)­N 4 , Li 7 (Nb/Ta)­N 4 , , Li 7 MnN 4 , Li 7 PS 6 , Na 6 MnCl 8 , Na 6 CdCl 8 , and Na 6 PbO 4 , which have been studied as electrodes or solid-state electrolytes (SSEs) in secondary batteries. The SSEs with high ionic conductivity are currently under intensive study. The incorporation of dilute elements in Li or Na binary compounds, such as their oxides, sulfides, and nitrides, can introduce Li or Na vacancies, which facilitate the ionic conduction.…”
mentioning
confidence: 99%
“…Some DECs found in our search are Li- or Na-rich, e.g., Li 6 (Mo/W)­N 4 , Li 7 (Nb/Ta)­N 4 , , Li 7 MnN 4 , Li 7 PS 6 , Na 6 MnCl 8 , Na 6 CdCl 8 , and Na 6 PbO 4 , which have been studied as electrodes or solid-state electrolytes (SSEs) in secondary batteries. The SSEs with high ionic conductivity are currently under intensive study. The incorporation of dilute elements in Li or Na binary compounds, such as their oxides, sulfides, and nitrides, can introduce Li or Na vacancies, which facilitate the ionic conduction.…”
mentioning
confidence: 99%