We show that any knot which is smoothly the closure of a 3-braid cannot be Lagrangian concordant to and from the maximum Thurston-Bennequin Legendrian unknot except the unknot itself. We use Murasugi's classification of 3-braids to rule out large classes of closures of 3-braids from candidacy using a variety of techniques from smooth, symplectic and contact topology. For the remaining family of braids, we draw Weinstein handlebody diagrams of particular symplectic fillings of their branched double covers. We use the Legendrian contact homology differential graded algebra of the links in these diagrams to compute the symplectic homology of these fillings to derive a contradiction. As a corollary, we find an infinite family of rational homology spheres which do not embed in R 4 as contact type hypersurfaces.