By miniaturizing electrode geometries high electric fields can be produced using modest voltages. A planar array of 20 m wide gold electrodes, spaced 20 m apart, is made on a sapphire substrate. A voltage difference of up to 350 V is applied to adjacent electrodes, generating an electric field that decreases exponentially with distance from the substrate. This microstructured array can be used as a mirror for polar molecules and can be rapidly switched on and off. This is demonstrated by retroreflecting a beam of state-selected ammonia molecules with a forward velocity of about 30 m=s. DOI: 10.1103/PhysRevLett.93.020406 PACS numbers: 03.75.Be, 33.55.Be, 33.80.Ps, 39.10.+j Miniaturizing current carrying structures has proven to be a very successful strategy for atom optics [1,2]. Microfabricated wires on surfaces allow one to exert extremely high magnetic forces on atoms using only moderate currents. A variety of microfabricated atom optical elements such as mirrors [3], guides [4], conveyer belts, and traps [5] have been realized. The integration of many of these devices into one circuit offers novel and exciting possibilities for quantum computation and atom interferometry [6,7].Miniaturizing charge carrying structures to manipulate polar molecules is equally promising. Using microstructured electrodes large electric fields and large field gradients can be generated with only moderate voltages. The interaction of polar molecules with electric fields is orders of magnitude stronger than the interaction of atoms with magnetic fields, and one can easily construct potentials on the order of a Kelvin. This allows one to design microstructured electrodes to manipulate cold polar molecules as produced, for instance, via buffer gas loading [8], Stark deceleration [9], collisions [10], or photoassociation [11]. The rotational and vibrational degrees of freedom as well as the (anisotropic) dipole-dipole interaction of polar molecules offer novel possibilities for interferometry and quantum computation [12].In this Letter, we experimentally demonstrate a microstructured switchable mirror for polar molecules. It is well known that a planar array of equidistant electrodes with a voltage difference between adjacent electrodes produces an electric field that decays exponentially with the distance from the surface. Such an array can therefore be used as an electrostatic mirror for polar molecules in so-called low-field seeking quantum states [13]. The principle of an electrostatic mirror was first discussed by Gordon as a means to select slow molecules [14]. Later this geometry was discussed in much more detail by Opat and co-workers [15,16], who experimentally demonstrated an electrostatic mirror by reflecting a beam of chloromethane (CH 3 Cl) from it at grazing angles of incidence. In the experiments reported here we demonstrate reflection of a cold beam of state-selected polar molecules from a microstructured electrostatic mirror under normal incidence. The mirror consists of an interdigitated structure of 20 m wide gol...