Recent data on deuterium retention in carbon fibre composites and tungsten both irradiated with D ions and exposed to D plasmas are presented. Deuterium depth profiles measured up to depths of 7-14 µm allow understanding the mechanism which is responsible for the hydrogen isotope trapping in these materials. The depth at which deuterium is retained in W can be divided into three zones: (i) the near-surface layer (up to a depth of 0.2-0.5 µm depending on ion energy), (ii) the sub-surface layer (from ~0.5 to ~2 µm), and (iii) the bulk (> 5 µm). Low-energy D ion irradiation modifies the W structure to depths of up to about 5 µm, both for W single crystals and polycrystalline W. The high D concentration (0.1-0.3 at.%) at depths of 1-3 µm relates to accumulation of D 2 molecules in vacancy clusters and voids. These defects are supposed to be generated due to plastic deformation of the W surface caused by deuterium supersaturation within the near-surface layer.