growing use of solar energy in steam generation techniques. [8][9][10] Steam generation is a crucial energy-intensive step in seawater desalination, which is typically followed by water vapor condensation to collect the desalinated water. By wielding interfacial evaporator to localize solar heat and boil sea water, steam (clean water) can be produced at a significantly higher rate than naturally ubiquitous evaporation process without the support of solar absorbers. [1,11,12] Of late, with a wide variety of new solar-absorber materials mushrooming, the solar desalination approach has begun to bear fruit. [13][14][15][16][17][18] To maximize the evaporation rate (ER) which is a key performance metric of solar steam generators, enormous efforts are underway, primarily focused on enhancing the light absorption, heat management, and water transport. [1,19] However, current studies often overlook the impacts from environment and the system itself. The understanding of the system-ambience interplay is still lacking in this area. Those neglectful factors, such as humidity that broadly changes with place and time, may be capable of manipulating the solar evaporation process. However, quite opposite to the common notion that the relative humidity (RH) affects ER, recent reports have confirmed that the solar evaporation is still able to maintain a high rate even when the RH greatly increases, [20,21] but understanding of how the evaporation can be sustained under such high humidity is still inadequate. [22] It is therefore more pressing to systematically study how the various system/ambient factors influence the evaporation process than to engineer a new solar absorber material, which sums up the motive of this work.This work shines light on the roles of relative humidity level of the ambience/system, waterlogged surface level, specific weight, carbonization thickness, and water salinity in influencing the water evaporation in a solar steam generation system, where microchanneled balsa wood was employed as an ideal research model for quantitative comparisons. Focusing on the system geometry and ambient conditions, the study aims to uncover the insights of the interplay between solar steam generation and practical operating environment, and provide constructive strategies for performance optimization of solar steam generators without any further sophisticated modifications on materials or system design. Solar steam generation as an emerging solar desalination technology has drawn tremendous research attention owing to its enticing prospects in tackling the rising water crisis across the globe. Despite the numerous reports on materials with high evaporation rates, little is known about how the system geometry and ambient conditions impact the evaporation rate. The ambient relative humidity (RH), which can potentially impact on the evaporation process in the system is one such element that is not well studied. In this work, microchanneled balsa wood is employed as the research model in the quantitative investigations of these ...