Trends and Prospects in UiO‐66 Metal‐Organic Framework for CO₂ Capture, Separation, and Conversion

Abstract

Among thousands of known metal‐organic frameworks (MOFs), the University of Oslo's MOF (UiO‐66) exhibits unique structure topology, chemical and thermal stability, and intriguing tunable properties, that have gained incredible research interest. This paper summarizes the structural advancement of UiO‐66 and its role in CO2 capture, separation, and transformation into chemicals. The first part of the review summarizes the fast‐growing literature related to the CO2 capture reported by UiO‐66 during the past ten years. The second part provides an overview of various advancements in UiO‐66 membranes in CO2 purification. The third part describes the role of UiO‐66 and its composites as catalysts for CO2 conversion into useful products. Despite many achievements, significant challenges associated with UiO‐66 are addressed, and future perspectives are comprehensively presented to forecast how UiO‐66 might be used further for CO2 management.

A Review of Supercapacitors: Materials Design, Modification, and Applications

“…Photovoltaic power production is one of the most energy-efficient technologies [254,255] in photo-SC, and the changing power of the solar cells is supplied with a SC [256,257]. SCs with a photoactive layer and a huge capacity layer is implemented on a single computer.…”

“…The hydrogenated ATOs' Cs (area) varied from 1.0 mF/cm 2 to 1 mA/cm 2 . Photo-SCs with optimal storage productivity (about 1.64%), strong cycle power, and rapid response time have shown high photoelectric conversion efficiency [256,257].…”

Screening Metal–Organic Frameworks for Separation of Binary Solvent Mixtures by Compact NMR Relaxometry

“…Once the correlation curves are established following the measurement and analysis of the CPMG decays, and the fit function for the correlation curve identified, a process which takes around 1 h for each mixture, the separation power of a particular MOF can be quantified within few minutes. UiO-66(Zr) (Figure 3) was chosen as a model MOF to test our methodology in the view of its high thermal, mechanical, and chemical stability, well-controlled synthesis procedure, and great promise in the field of separation [23,[48][49][50][51][52][53][54]. This MOF is built from Zr6O6(CO2)12 nodes connected via terephthalate linkers.…”

Recent Progress in Carbonaceous and Redox‐Active Nanoarchitectures for Hybrid Supercapacitors: Performance Evaluation, Challenges, and Future Prospects

“…MOFs have sparked much research interest because of their inherent advantages, such as high SSA, large pores, controllable morphology, and multifunctionalities. They are considered one of the best links between energy storage and nanotechnology [188,249–254] . Due to such outstanding properties, when used as electrode materials, MOFs can provide superior HSCs energy storage performance, [255] as shown in Figure 18(l).…”

“…They are considered one of the best links between energy storage and nanotechnology. [188,[249][250][251][252][253][254] Due to such outstanding properties, when used as electrode materials, MOFs can provide superior HSCs energy storage performance, [255] as shown in Figure 18(l). He et al [256] prepared a high electronic conductivity and increased active sites, material with the coupling of NiCo-MOF and NiCoP heterostructures, which delivered excellent electrochemical performance (728 C/g specific capacity at a specific current of 1.0 A/g).…”