This study examines the spatio-temporal evolution of bioclimatic belts in peninsular Spain and the Balearic Islands from 1953 to 2022 using the World Bioclimatic Classification System and data from 3668 meteorological stations. Findings indicate a shift toward warmer and more arid conditions, with thermotypes showing an increase in mesomediterranean and thermomediterranean types and a decrease in mesotemperate and supratemperate types. Ombrotype analysis revealed a rise in semiarid types and a decline in humid and hyperhumid types. Significant changes occurred in climate transition zones and mountainous regions, where a process of “Mediterraneanisation”—a process characterised by the expansion of warmer and drier conditions typical of Mediterranean climates into previously temperate areas and/or an altitudinal rise in thermotypes—has been observed. The spatial variability of changes in ombrotypes was greater than that in thermotypes, with regions showing opposite trends to the general one. These results highlight the need for adaptive conservation strategies, particularly in mountainous and climate transition areas, where endemic species may face increased vulnerability due to habitat loss and fragmentation. The results of this study provide insight into how climate change is affecting bioclimatological conditions in the Iberian Peninsula and the Balearic Islands.