Triaqua(4-hydroxypyridine-2,6-dicarboxylato-κ<sup>3</sup><i>N,O,O</i>′)zinc(II)–acetonitrile–water(1/0.25/1)

H9a-Acr) 2 [Ni(hypydc) 2 ]•4H 2 O (1), (H9a-Acr) 2 [Co(hypydc) 2 ]•3H 2 O (2), (H9a-Acr) [Cr(hypydc) 2 ]•3H 2 O (3), and (H9a-Acr) 2 [Cd(hypydc) 2 ]•3H 2 O ( 4) compounds (H 2 hypydc = 2,6-dicarboxy-4-hydroxypyridine or chelidamic acid; 9a-Acr = 9-aminoacridine) were synthesized via proton transfer and characterised by elemental analysis, IR spectroscopy, and single crystal X-ray diffraction techniques. Thermogravimetric analysis (TGA) was carried out on compounds 1 and 2. Compounds 1-4 have distorted octahedral geometries with two hypydc 2− ions coordinated as tridentate ligands to each metal ion through one oxygen atom of each carboxylate group and the nitrogen atom of the pyridine ring. In the compounds, strong hydrogen bonds between anionic, cationic, and water fragments and especially the different natures of the π + ⋯π − and π − ⋯π − stacking interactions play important roles in the construction of threedimensional supramolecular frameworks which have been analysed in detail. The smaller trans N-M-N angle observed in 3 as compared with the others has been analysed using DFT calculations. Solution studies have also been performed to understand the behaviour of the ternary systems M n+ -H 2 hypydc-9a-Acr in aqueous solution.

show abstract

(2,9-Dimethyl-1,10-phenanthroline)(4-hydroxypyridine-2,6-dicarboxylato)copper(II) trihydrate

Soleimannejad

Aghabozorg

Manteghi

et al. 2009

Acta Cryst E

View full text Add to dashboard Cite

In the title complex, [Cu(C7H3NO5)(C14H12N2)]·3H2O, there are two independent neutral molecules of the Cu complex along with six molecules of water of hydration in the asymmetric unit. The CuII atoms in each complex adopt a distorted square-pyramidal coordination geometry being pentacoordinated by one N and two O atoms of 4-hydroxypyridine-2,6-dicarboxylate anions and two N atoms of 2,9-dimethyl-1,10-phenanthroline (dmp) molecules. In the crystal structure, there are O—H⋯O and C—H⋯O hydrogen bonds and five π–π stacking interactions with centroid–centroid distances in the range 3.620 (1)–3.712 (1) Å. In addition, a C—H⋯π interaction between a heterocyclic ring of dmp is observed to reinforce the crystal cohesion.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Triaqua(4-hydroxypyridine-2,6-dicarboxylato-κ³N,O,O′)zinc(II)–acetonitrile–water(1/0.25/1)

Abstract: Key indicatorsSingle-crystal X-ray study T = 293 K Mean '(C±C) = 0.002 A Ê H-atom completeness 38% Disorder in solvent or counterion R factor = 0.052 wR factor = 0.154 Data-to-parameter ratio = 11.1 For details of how these key indicators were automatically derived from the article, see

Cited by 4 publications

References 14 publications

Synthesis, characterization, spectroscopic, crystal structures and solution studies of two coordination compounds of zinc(II) and iron(III) based on chelidamic acid and acridine

Synthesis, characterization, spectroscopic, crystal structures and solution studies of two coordination compounds of zinc(II) and iron(III) based on chelidamic acid and acridine

Crystal engineering with coordination compounds of 2,6-dicarboxy-4-hydroxypyridine and 9-aminoacridine fragments driven by different nature of the face-to-face π⋯π stacking

(2,9-Dimethyl-1,10-phenanthroline)(4-hydroxypyridine-2,6-dicarboxylato)copper(II) trihydrate

Contact Info

Product

Resources

About

Triaqua(4-hydroxypyridine-2,6-dicarboxylato-κ3N,O,O′)zinc(II)–acetonitrile–water(1/0.25/1)

Abstract: Key indicatorsSingle-crystal X-ray study T = 293 K Mean '(C±C) = 0.002 A Ê H-atom completeness 38% Disorder in solvent or counterion R factor = 0.052 wR factor = 0.154 Data-to-parameter ratio = 11.1 For details of how these key indicators were automatically derived from the article, see

Cited by 4 publications

References 14 publications

Synthesis, characterization, spectroscopic, crystal structures and solution studies of two coordination compounds of zinc(II) and iron(III) based on chelidamic acid and acridine

Synthesis, characterization, spectroscopic, crystal structures and solution studies of two coordination compounds of zinc(II) and iron(III) based on chelidamic acid and acridine

Crystal engineering with coordination compounds of 2,6-dicarboxy-4-hydroxypyridine and 9-aminoacridine fragments driven by different nature of the face-to-face π⋯π stacking

(2,9-Dimethyl-1,10-phenanthroline)(4-hydroxypyridine-2,6-dicarboxylato)copper(II) trihydrate

Contact Info

Product

Resources

About

Triaqua(4-hydroxypyridine-2,6-dicarboxylato-κ³N,O,O′)zinc(II)–acetonitrile–water(1/0.25/1)