Triazole Containing Salicylimine Linked Organosilocane for Recognition of Ce3+ Ions in Aqueous Media

Singh, Gurjaspreet; Shilpy,; Singh, Akshpreeet; Diksha, .; Satija, Pinky; Sushma, .; Mohit, .; Kaur, Jashan Deep; Singh, K.

doi:10.1007/s10904-020-01780-7

Cited by 4 publications

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“…1,2,3-Triazoles are a rising class of heterocyclic compounds that have received significant attentiveness from the past few years because of their versatile applications in biochemical, pharmaceutical, sensing and material sciences. [1][2][3][4][5][6][7] The copper (I) catalyzed synthesis of 1,2,3-triazoles from azides and terminal alkynes is an increasingly common method for rapid synthesis of organic and bioorganic compounds in high yields and purity. [8][9][10][11] Therefore, the well recognized click route was followed to generate 1,2,3-triazole derivatives.…”

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confidence: 99%

Synthesis and Characterization of Antioxidant Biphenyl Appended 1,2,3‐Triazoles as Potential Chemo‐Sensor for Sn²⁺ Ions: Excellent Selectivity and Low Detection Limit

et al. 2021

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Designing of chemo-sensors is a new scope of intrigue among researchers. After inspecting the beneficial and harmful effects of Sn(II) metal ions in living species, 1,2,3-Triazole based chemo-sensor 4 a have been synthesized via click route. In the current article, literarily new 1,2,3-Triazoles (4 a-4 d) have been synthesized and identified via various spectroscopic means such as NMR( 1 H & 13 C), IR and mass spectrometry. Triazole 4 a was explored for recognition properties via absorption and emission spectroscopy and found specific and selective for Sn(II) metal ions. The recognition of Sn 2 + metal ions by probe 4a was not interfered because of other tested metal cations. The probe has very low detection limit of 0.47 × 10 À 7 M and 3.8 × 10 À 9 M via ultraviolet and fluorescence spectroscopy respectively which is lower than many previously reported sensors. The BÀ H plot and stern volmer's plot confirmed a high binding affinity between probe 4a and tin (II) metal ion. The association constant (K a ) and stern volmer constant (K sv ) were calculated as 13.36 × 10 5 M À 1 and 12.6 × 10 6 M À 1 from BÀ H plot and stern volmer's plot respectively. The Stoichiometric ratio between chemo-sensor 4 a and Sn 2 + metal ions was confirmed as 1 : 1 by the job's plot. Moreover, in this study, the synthesized compounds 4(a-d) were examined for their antioxidant properties. The total antioxidant activity (TAA) results indicate that the synthesized triazoles 4(a-d) found to be excellent postulant for radical scavenging. TAA values for 4 a, 4 b, 4 c and 4 d are found to be 4.65 � 0.2, 6.79 � 0.3, 6.29 � 0.2, 5.06 � 0.1 (mM)(eq. ascorbic acid) per 100 mM of particle respectively.

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Section: Introductionmentioning

confidence: 99%

Synthesis and Characterization of Antioxidant Biphenyl Appended 1,2,3‐Triazoles as Potential Chemo‐Sensor for Sn²⁺ Ions: Excellent Selectivity and Low Detection Limit

et al. 2021

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Highly sensitive and low-cost detecting and recovering Ce3+ from ammonia nitrogen wastewater using bio-inspired nanochannel/membrane

Ma,

Tan,

Yuan

et al. 2023

Chemical Engineering Journal

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Design of pyrene functionalized triazole linked organosilane for specific detection of Ce3+ ions

Singh

Shilpy

Singh³

et al. 2021

Journal of Molecular Structure

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Triazole Containing Salicylimine Linked Organosilocane for Recognition of Ce3+ Ions in Aqueous Media

Cited by 4 publications

References 26 publications

Synthesis and Characterization of Antioxidant Biphenyl Appended 1,2,3‐Triazoles as Potential Chemo‐Sensor for Sn²⁺ Ions: Excellent Selectivity and Low Detection Limit

Synthesis and Characterization of Antioxidant Biphenyl Appended 1,2,3‐Triazoles as Potential Chemo‐Sensor for Sn²⁺ Ions: Excellent Selectivity and Low Detection Limit

Highly sensitive and low-cost detecting and recovering Ce3+ from ammonia nitrogen wastewater using bio-inspired nanochannel/membrane

Design of pyrene functionalized triazole linked organosilane for specific detection of Ce3+ ions

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Triazole Containing Salicylimine Linked Organosilocane for Recognition of Ce3+ Ions in Aqueous Media

Cited by 4 publications

References 26 publications

Synthesis and Characterization of Antioxidant Biphenyl Appended 1,2,3‐Triazoles as Potential Chemo‐Sensor for Sn2+ Ions: Excellent Selectivity and Low Detection Limit

Synthesis and Characterization of Antioxidant Biphenyl Appended 1,2,3‐Triazoles as Potential Chemo‐Sensor for Sn2+ Ions: Excellent Selectivity and Low Detection Limit

Highly sensitive and low-cost detecting and recovering Ce3+ from ammonia nitrogen wastewater using bio-inspired nanochannel/membrane

Design of pyrene functionalized triazole linked organosilane for specific detection of Ce3+ ions

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Synthesis and Characterization of Antioxidant Biphenyl Appended 1,2,3‐Triazoles as Potential Chemo‐Sensor for Sn²⁺ Ions: Excellent Selectivity and Low Detection Limit

Synthesis and Characterization of Antioxidant Biphenyl Appended 1,2,3‐Triazoles as Potential Chemo‐Sensor for Sn²⁺ Ions: Excellent Selectivity and Low Detection Limit